Self-rolled TiO_2 microscroll/graphene composite for electrochemical dopamine sensing

Dopamine is an important neurotransmitter,and nonenzyme electrochemical sensor of dopamine detection based on highly active material is urgently demanded.In this work,an electrochemical sensor with high sensitivity and selectivity based on self-rolled TiO_2microscroll/graphene composite was developed and validated for dopamine sensing.The device exhibited a superior performance for dopamine detection with a detection limit of 4.25×10~(-9)mol L~(-1),and in the dopamine concentration range of 0.06–90μmol L~(-1),the oxidation currents increased linearly with the concentration.The remarkable performance enhancement was mainly ascribed to the increased surface area due to the porous surface of the TiO_2nanomembrane and highly conductive graphene therein.In addition,we have demonstrated that the sensor could be effectively used on detecting dopamine concentrations in urine samples.Our work demonstrates that the current microscroll-based device is promising in the field of real-time health monitoring for future human community.     

Solid-state Synthesis of Carbon-nanostructures

1 Results In addition to single wall and multiwall carbon nanotubes[1], several structures,which are more or less related to fullerenes,including carbon nanohorns[2a], carbon nanospheres[2b] and onion like carbon structures[2c] have been reported.A new simple straight forward method to access some of these structures is the solid-state pyrolysis of different organometallic complexes in a sealed vessel,which led so far to carbon nanotubes[3a,b], carbon nanocables[3c] and onions[3d].     

Superhydrophobicity on Micro-and Nanostructured Polyolefin Surfaces:an Experimental and Theoretical Study

1 Results Simultaneous micro-and nanostructuring was prepared on polyolefin surfaces by injection molding.The molds were made of electropolished aluminum foil where the micropatterns were structured with a custom made robot.Nanopatterns were subsequently created on the molds by oxidizing the aluminum surface electrochemically in polyprotic acid.The preparation technique allowed simultaneous control of the dimensions of the micro-and nanostructures.Structuring has a remarkable effect on the contact angle...     

基于扫描电子显微镜的单根一维纳米材料原位场发射性能研究

基于扫描电子显微镜和纳米探针技术,展示了一维纳米材料原位场发射的测量方法和实例。实验以钨针尖为接收极,纳米材料为发射极,通过结合扫描电子显微镜的实时成像功能,纳米探针的精确操纵及电学测量技术以及激光辐照功能,系统研究了极间距离D、形貌变化、吸附气体和激光注入对单根多壁碳纳米管和氧化锌纳米线场发射性能的影响。结果表明,当D远小于纳米材料长度L的3倍时,D越小,开启场强和阈值场强越大,场发射性能越弱。此外,纳米线尖端曲率半径越大,场增强因子越小,场发射性能越弱。研究还发现O2的脱附和激光辐照有助于纳米材料场发射性能的提高。     

分散H∞低阶控制器在不确定电力系统中的应用

提出了一种新的方法为具有不确定性的实际电力系统设计分散鲁棒H∞阻尼控制器。采用多胞型模型将系统运行状态的各种变化描述为以若干个典型运行参数为顶点的凸集。分散H∞控制器的设计可以归结为基于同伦参数法的两个线性矩阵不等式的求解问题。所提的方法可以得出较低阶的鲁棒控制器，具有工程实用性。将其与系统模型降阶法相结合，可进一步减轻计算负担，进而适用于实际电力系统的控制器求解。算法分别用于SVC的分散附加阻尼控制器和19机IEEE标准测试系统的PSS设计。算例结果表明，分散控制器相互协调，不但显著地提升系统的阻尼比，使其具有良好的抗干扰能力，且对于严重故障后产生的持续振荡具有很好的抑制作用。     

汉语元音的非线性预测

最近研究表明非线性的局部模型是最精确的混沌时间序列预测方法之一．同时有研究表明汉语的产生过程包含非线性．传统的语音处理技术忽视了语音中可能存在的非线性结构，因而限制了处理能力的进一步提高．对汉语元音／a／和／u／的细致相空间分析结果表明，汉语元音的重构相空间有类似于混沌吸引子的结构．根据汉语元音发声过程的非线性特性，进一步对其进行相空间的局部线性预测分析，计算了预测误差随预测步长的关系曲线，讨论了嵌入维数对预测性能的影响，并且与传统的线性方法作了比较．结果表明，尽管非线性的局域线性预测法存在计算开销大的问题，但其预测视野要远大于线性预测法，总体预测性能明显优于线性预测法．     

Nanostructural evolution of Zn by dry roller vibration milling at room temperature

It remains open to date to produce stable nanostructures of single element by dry mechanical method at room temperature on a large scale. Here we report nanostructural evolution of zinc by dry roller vibration milling at room temperature, which leads to structurally near perfect zinc flakes sized 3?5 nm in diameter. The synthesized nanostructures are single crystalline, transparent, uniform, randomly oriented, almost equiaxed, and mostly free from defects. The evolution seems to open a way to optimize zinc nanostructures by the mechanical method, offer valuable references to prepare nanostructures of other metals optimally, and shed light on how to lower the size limit by mechanical milling. Single elemental metal nanostructures with excellent properties give rise to new opportunities in scientific research and development of nanotechnology.     

环形石墨烯纳米结构的等离激元激发

基于含时密度泛函理论,研究了环形石墨烯纳米结构的等离激元激发.在低能共振区,和同尺度大小的石墨烯纳米结构相比,环形石墨烯纳米结构光谱的主要吸收峰发生了红移;体系中有两种主要的等离激元共振模式:低能成键模式和高能反键模式.此外,环形石墨烯纳米结构的等离激元激发对体系尺度的大小也有一定的依赖性.     

低维Hom-Jacobi-Jordan代数的分类

先定义Hom-Jacobi-Jordan代数, 然后用这类代数线性映射的Jordan标准形和待定系数法给出低维Hom-Jacobi-Jordan代数的同构类.